Train those people responsible for different parts of the orientation on their duties, when necessary. The HR person will be coordinating the orientation program, but not be executing each part of it. For example, all job-specific information may be given by the direct manager; information about payroll, leave and attendance might be given by the administration, instructions on tracking work may be given by a team member.
This can be organised in a general staff training or by sitting down with each staff member seperately, depending on the size of the organisation.
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